A mechanistic proposal for the protodeboronation of neat boronic acids: boronic acid mediated reaction in the solid state.

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Noonan, G and Leach, AG (2015) A mechanistic proposal for the protodeboronation of neat boronic acids: boronic acid mediated reaction in the solid state. Organic and Biomolecular Chemistry, 13. pp. 2555-2560. ISSN 1477-0539

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Publisher URL: http://dx.doi.org/10.1039/c4ob02543a

Abstract

A combined experimental and computational study suggests that a reduction in the entropy of activation in the solid state can lead to the protodeboronation of boronic acids.

Item Type:	Article
Uncontrolled Keywords:	0304 Medicinal And Biomolecular Chemistry, 0305 Organic Chemistry, 1115 Pharmacology And Pharmaceutical Sciences
Subjects:	Q Science > QD Chemistry
Divisions:	Pharmacy and Biomolecular Sciences
Publisher:	Royal society of Chemistry
Related URLs:	http://www.ncbi.nlm.nih.gov/pubmed/25604694
Date of acceptance:	9 January 2015
Date Deposited:	30 Jan 2015 16:17
Last Modified:	04 Sep 2021 14:43
DOI or ID number:	10.1039/c4ob02543a
URI:	https://ljmu-9.eprints-hosting.org/id/eprint/352

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